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KARPEN PILE

Started by Philip Hardcastle, May 22, 2014, 10:41:32 PM

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MarkE

#145
July 13, 2014, 10:59:54 PM
Quote from: profitis on July 13, 2014, 04:54:46 AM
@mark E yes ofcourse entropy increases with time here.do you not think that concentration cells belong to the universe?I'm going to tell you what your favourite(and my favourite) textbook wikipedia told me: electrochemical entropy takes precidence over temperature entropy.gravblock is correct,'entropy is the ultimate order'
Really?  You are going to go with "entropy is the ultimate order"???  Entropy dear boy is a measure of how dispersed energy is.  Saying as you have that: "entropy is the ulimate order" is like saying "Length is the ultimate size."  It makes no sense. 

gravityblock

#146
July 14, 2014, 12:04:39 AM
Quote from: MarkE on July 13, 2014, 10:59:54 PM
Really?  You are going to go with "entropy is the ultimate order" ???  Entropy dear boy is a measure of how dispersed energy is.  Saying as you have that: "entropy is the ulimate order" is like saying "Length is the ultimate size."  It makes no sense.

MarkE,

Does a reversible chemical reaction proceed in both directions?

Gravock
Insanity is doing the same thing over and over again, and expecting a different result.

God will confuse the wise with the simplest things of this world.  He will catch the wise in their own craftiness.

MarkE

#147
July 14, 2014, 01:39:57 AM
Quote from: gravityblock on July 14, 2014, 12:04:39 AM
MarkE,

Does a reversible chemical reaction proceed in both directions?

Gravock
Now you are spamming.

gravityblock

#148
July 14, 2014, 02:38:22 AM
Quote from: MarkE on July 14, 2014, 01:39:57 AM
Now you are spamming.

You are grasping for straws!  Answer the question MarkE!

Gravock
Insanity is doing the same thing over and over again, and expecting a different result.

God will confuse the wise with the simplest things of this world.  He will catch the wise in their own craftiness.

pomodoro

#149
July 14, 2014, 04:27:18 AM
Good news profitis, I now have a silver electrode.  I did a few CVs of the Pd, Pt and Ag in 1MKOH under N2.   You can see the overvoltage required on the Ag for yourself.  Voltages are vs Ag/AgCl.

When I finished the scans I connected  the Ag and Pd together. The current jumped from a few mA very quickly to uA and then to zero. No galvanic corrosion going on under N2.  Recovery was very poor when disconnected.


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