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quentron.com

Started by Philip Hardcastle, April 04, 2012, 05:00:30 AM

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profitis

yay! Sarkeizen has forgiven me!under section nernst equation there in that book you,l see it written that the tendency for an electrochemical half-reaction to occur depends on concentration of the species involved thus we can build a cell with 2 same half-reactions at different concentrations of 1 or more species thus for 2 of same half reactions: 1/2 O2 + 2H+ + 2e- = H2O  and differing O2 concentrations on the electrodes at equal pressure we get E=0.059/n log c1 O2(atm a)/c2 O2(atm a) at 25degreesC and since c1 = c2 after transfer of gas we must have pressure change c1(atm a)=c2(atm b) at equilibrium and since kelvin statement cannot apply to a situation where we end up with a gas pressure differential spontaneously without paying for it with a heat differential to begin with we are forced to conclude that kelvin statement need not apply here @sarkeizen  no kelvin statement equals perpetual motion.perpetualy

sarkeizen

Quote from: profitis on January 14, 2014, 06:42:04 PM
yay! Sarkeizen has forgiven me!under section nernst equation there in that book you,l see it written that the tendency for an electrochemical half-reaction to occur depends on concentration of the species involved thus we can build a cell with 2 same half-reactions at different concentrations of 1 or more species thus for 2 of same half reactions: 1/2 O2 + 2H+ + 2e- = H2O  and differing O2 concentrations on the electrodes at equal pressure we get E=0.059/n log c1 O2(atm a)/c2 O2(atm a) at 25degreesC and since c1 = c2 after transfer of gas we must have pressure change c1(atm a)=c2(atm b) at equilibrium and since kelvin statement cannot apply to a situation where we end up with a gas pressure differential spontaneously without paying for it with a heat differential to begin with we are forced to conclude that kelvin statement need not apply here @sarkeizen  no kelvin statement equals perpetual motion.perpetualy
Line breaks please. Not even going to bother reading if you don't take this seriously troll-boy.

orbut 3000

qUesti0n_|4|_@'pr0fitis'/ cAn_y0u_explain_|plz|_why_y0u_keep_writing_y0ur_messages_in_such_a_weird_manner_|?|/ iT's_n0t_as_easy_t0_decipher_as_standard_n0tati0n_and_i_w0nder_why_y0u}re_d0ing_it_that_way/ tHanks/

sarkeizen

Quote from: orbut 3000 on January 14, 2014, 09:28:41 PM
qUesti0n_|4|_@'pr0fitis'/ cAn_y0u_explain_|plz|_why_y0u_keep_writing_y0ur_messages_in_such_a_weird_manner_|?|/ iT's_n0t_as_easy_t0_decipher_as_standard_n0tati0n_and_i_w0nder_why_y0u}re_d0ing_it_that_way/ tHanks/
Seems like an attempt to hide his identity.

Marsing

Quote from: profitis on January 13, 2014, 05:28:39 AM
if i used that much space then what are you complaining about @marsing

nothing, i need 9950bux back + 100% delay Fee