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KARPEN PILE

Started by Philip Hardcastle, May 22, 2014, 10:41:32 PM

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pomodoro

#485
August 13, 2014, 04:41:11 AM
Quote from: profitis on August 13, 2014, 02:48:30 AM
Also note that corrosion current is impossible.according to standard table of potentials nickel must corrode by a exponentialy huge margin.

But now it has a film of nickel Hydroxide, so the tables are no longer valid.

profitis

#486
August 13, 2014, 05:01:02 AM
Yes @mark E.gas is dispersed,heat absorbed,potentials re-constituted.its an EQUILIBRIUM POTENTIAL DIFFERENCE.karpen gave same explanation.

profitis

#487
August 13, 2014, 05:04:30 AM
Exactly @pomodoro.nickel is so inert in alkali it can go cathodic to platinum.this justifies its use for oxygen evolution in the MnO2/nickel setup where it is anodic

profitis

#488
August 13, 2014, 05:07:47 AM
These cells have tens of thousands years shelflife.that in itself is violation of 2nd law.they are negentropic

MarkE

#489
August 13, 2014, 05:15:04 AM
Quote from: profitis on August 13, 2014, 05:01:02 AM
Yes @mark E.gas is dispersed,heat absorbed,potentials re-constituted.its an EQUILIBRIUM POTENTIAL DIFFERENCE.karpen gave same explanation.
Over what temperature range does your preferred cell chemistry supposedly pull heat from the surroundings??  Will it work between 50C and 0C?  25C and 10C?
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