KARPEN PILE

[profitis]

I can give you more such examples of spontanteously- reversed galvanic couples if you want @mark E

[MarkE]

It doesn't work under argon or nitrogen,only air or oxygen,which means o2 is without a shred of doubt involved in its electrode reactions.this is to be expected because the oxygen concentration is much larger at the nickel than at the platinum.after o2 concentrations are leveled out on discharge,opening switch allows recharge and re-distribution of original oxygen concentrations spontaneously. 100% reversable catalytic oxygen spillover from nickel onto platinum in this case.against kelvin rule.

Is it your contention that the oxygen concentrations return to their disparate levels without application of outside energy?

[profitis]

Electrochemical entropy will squash gas from the cathode onto anode at expense of temperature entropy on discharge.spontaneous heat inflow from ambient without need for temp gradient will disperse gas on recharge. You want to make as much power density as you can to be able to test these cells adequetly against the 2lot.

[profitis]

For power density on an o2 karpen I suggest the MnO2 pyrolusite/ nickel(blackened)/NaOH/air variety,easy to make and cheap.in this case nickel is your anode(submerged)

[MarkE]

Electrochemical entropy will squash gas from the cathode onto anode at expense of temperature entropy on discharge.spontaneous heat inflow from ambient without need for temp gradient will disperse gas on recharge. You want to make as much power density as you can to be able to test these cells adequetly against the 2lot.

So, is it your claim that the materials in the cell operating at the same temperature as the surroundings absorb heat from the surroundings, and in doing so generates a disparity in the O₂ concentrations that exist in the vicinity of each electrode?