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Overunity Machines Forum



The problem of freezing

Started by buzneg, December 01, 2007, 02:23:30 PM

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0 Members and 3 Guests are viewing this topic.

bosr

Quote from: MrMag on December 04, 2007, 08:48:10 PM
where I live the water will freeze during the winter. How can I prevent that?

Water in a glass, toilet, bath tub, pond ????

People around here that have fish ponds put in a bubbler. As long as the water is moving it will be harder to freeze.

My guess is that it would not be very efficient to agitate water in a car while it sits dormant.

ResinRat2

Looking up the properties of an electrolyte such as Potassium Hydroxide:

http://en.wikipedia.org/wiki/Potassium_hydroxide

We see that it has a saturation point in water of 1.0 grams KOH able to dissolve in only 0.5 grams of water.

The freezing point depression of water can be calculated from the molal freezing point constant for water which is defined as:

Kf = 1.86 ?C  -  kg. water 
                Moles Solute

So if we make a Table with the calculated values for the freezing point depression of water as Potassium Hydroxide is added we get the following:

%KOH in Water   Freezing Point (?C)   Freezing Point (?F)  
         0                         0.0                      32.0
       10                        -3.7                      25.4
       20                        -8.3                      17.1
       30                       -14.2                       6.4
       40                       -22.1                      -7.8
       50                       -33.1                    -27.7

Once you start getting above 40% KOH in water the viscosity of the solution starts to increase and that is why I stopped at 50% solids.

Theoretically the saturation point of KOH in water is 1.5grams KOH will dissolve in 0.5 grams of water. Calculating that freezing point depression we get a freezing point of:

(1.86?C ? kg water)    (1.0 grams KOH)  ( 1 mole KOH)     =  -66.3?C 
    ( Moles KOH)         (0.0005 kg water)  ( 56.1 g. KOH)

Which is -87?F.  Of course this is theoretical and doesn't take into account solubility changes at lower temperatures. I think the water would be of such high viscosity it would barely move, but it does show how salt based electrolyte can lower the freezing point of water on its own.

Research is the only place in a company where you can continually have failures and still keep your job.

I knew immediately that was where I belonged.

Cap-Z-ro


Axuelly, I was just kidding about the 'blue toilet brick' - and about drinking the water from the electrolyser...and now I hear people drink the water from the 'joe cell'.

Go figure huh :)

kyhydro

I think some type of alcohol would be best.  But your cell can't get hot or the alcohol would boil off and be burnt in the engine.  This wouldn't be an issue for the engine but you would have to replace the alcohol everytime you shut off your vehicle.
Ethanol boils around 172F, 78C and methanol 147F,64C.   Windshield washer fluid is mostly alcohol, HEET is methanol, some fuel stations sell ethanol (don't know the percents.) 


bosr

Thanks guys...I'll have a go at testing your ideas once I get my cell built and conditioned.  May be a while before I'm finished due to schedule, blah blah...

Do you suppose there's any way to store enough solar energy to heat the water?  Without making my car a rolling solar panel that is.