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Overunity Machines Forum



Selfrunning Free Energy devices up to 5 KW from Tariel Kapanadze

Started by Pirate88179, June 27, 2009, 04:41:28 AM

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qwekw

from book "Electromagnetic Compossibility, Second Edition  By Heinz M. Schlicke"

humb

If maybe someone knows about this video

FREE ENERGY SOLID STATE DEVICE Andrey from Russia

Did Andrey posted any plans of his device?

humb

I build kapagen that JLN posted on his website. It shows up that is fake. Those coils are useless. All work is made by microwawe transformer.

stivep

http://www.pnas.org/content/109/39/15663.abstract
Possible explanation of Andrea Rossi process:

Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production

AbstractThe design of molecular electrocatalysts for H2 oxidation and production is important for the development of
alternative renewable energy sources that are abundant, inexpensive, and environmentally benign.


Recently, nickel-based molecular electrocatalysts with pendant amines that act as proton relays for the nickel center were shown to effectively catalyze H2 oxidation and production. We developed a quantum mechanical approach for studying proton-coupled electron transfer processes in these types of molecular electrocatalysts. This theoretical approach is applied to a nickel-based catalyst in which phosphorous atoms are directly bonded to the nickel center, and nitrogen atoms of the ligand rings act as proton relays. The catalytic step of interest involves electron transfer between the nickel complex and the electrode as well as intramolecular proton transfer between the nickel and nitrogen atoms. This process can occur sequentially, with either the electron or proton transferring first, or concertedly, with the electron and proton transferring simultaneously without a stable intermediate. The electrochemical rate constants are calculated as functions of overpotential for the concerted electron-proton transfer reaction and the two electron transfer reactions in the sequential mechanisms. Our calculations illustrate that the concerted electron-proton transfer standard rate constant will increase as the equilibrium distance between the nickel and nitrogen atoms decreases and as the pendant amines become more flexible to facilitate the contraction of this distance with a lower energy penalty. This approach identifies the favored mechanisms under various experimental conditions and provides insight into the impact of substituents on the nitrogen and phosphorous atoms.


additional literature:
http://www.gamry.com/products/digielch-electrochemical-simulation-software/
charge-coupled chemical reactions such as proton coupled electron transfer (PCET)
http://en.wikipedia.org/wiki/Proton-coupled_electron_transfer


Wesley