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KARPEN PILE

Started by Philip Hardcastle, May 22, 2014, 10:41:32 PM

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profitis

If shiny part of silver sticks out electrolyte its no prob pomodoro.as long as black part submerged.it doesn't really matter even if part of the black is exposed to H2 because its overpotential remains quite invariant.this is the nice thing about spillover cells.you can shake em,kick em,even hold em upside down in wet electrolyte and they work fine.in nearly all of my experiments the black part of the Ag was partially exposed to H2 atmosphere and it didn't cause reduction of overpotential difference.H2 gas diffuses straight through electrolyte

profitis

@sarkeizen....watch...

profitis

@mark E yes ofcourse entropy increases with time here.do you not think that concentration cells belong to the universe?I'm going to tell you what your favourite(and my favourite) textbook wikipedia told me: electrochemical entropy takes precidence over temperature entropy.gravblock is correct,'entropy is the ultimate order'

profitis

@mark E..the electrochemical entropy chops a temperature gradient into the ambient until equilibrium. disengagement of switch throws system back into temperature entropy's hands and disperses any gas away from cathode.two interswitchable entropy states.

MarkE

Quote from: profitis on July 13, 2014, 10:23:14 PM
@mark E..the electrochemical entropy chops a temperature gradient into the ambient until equilibrium. disengagement of switch throws system back into temperature entropy's hands and disperses any gas away from cathode.two interswitchable entropy states.
LOL! It's always amusing when you decide to regress into incomprehensible grammar.  Perhaps you would like to state in plain English what you mean by:  "entropy chops a temperature gradient into the ambient", or "disengagement of switch throws system back into temperature entropy's hands".